Atoms, Elements and Compounds

Atomic Structure and the Periodic Table

ParticleRelative chargeMass (atomic mass)
Proton+11
Neutron01
Electron-1

Proton number: number of protons in an atom (and number of electrons in an atom)

Nucleon number: number of protons + neutrons in an atom.

Isotopes: atoms of same element with different no. of neutrons

  • E.g. Carbon 12 and Carbon 14.
  • Two types: non-radioactive isotopes and radioactive-isotopes which are unstable atoms that break down giving radiations
  • Medical use: cancer treatment (radiotherapy) -- rays kill cancer cells using cobalt-60
  • Industrial use: to check for leaks -- radioisotopes (tracers) added to oil/gas. At leaks radiation is detected using a Geiger counter.

In the periodic table

  • The proton number increases by 1 when you go to the right
  • When you go one element down, you increase proton number by 8 in the first 3 periods (transition elements not included)

Electrons are arranged in electron shells.

Atoms want to have full outer shells (full set of valency electrons), this is why they react.

Noble gases have full outer shells so they have no need to react.

Electron shell structure: 2, 8, 8, 18.

More reactive elements have a greater desire to have a full outer shell, so also form more stable compounds.

Bonding: the Structure of Matter

Element: substance that cannot be split into anything simpler, in a chemical reaction. Each element has a unique proton number.

Mixture: two or more elements mixed together but not chemically combined

Compound: substance in which two or more different elements are chemically combined

MetalsNon-metals
StrongBrittle
Good conductors of heat & electricityPoor conductors of heat & electricity (except graphite)
High m.p. and b.p.Lower m.p. and b.p. than metals
High densityLow density
Forms basic oxidesForms acidic oxides
Forms cations in reactionsForms anions in reactions
Malleable and ductile
Sonorous
Some are magnetic

Alloy: Mixture of two or more metals or mixture of one or more metal with a non-metal, to improve its properties

Ions and Ionic Bonds

Chemical bond formed by transfer of s from one atom to another

Metals lose s to form cations, non-metals gain s to form anions

Positive cations & negative anions attract to each other

Strong electrostatic force of attraction between positive cations and negative anions is called ionic bonding

PropertyReason
Form giant latticeCations and anions attract
High m.p. and b.p.Strong bonds between ions
Don't conduct electricity when solidIons can't move
Conduct electricity when molten/aqueousIons can move
Usually soluble in waterNot required

Molecules and Covalent Bonds

When atoms share s to obtain a noble gas electron structure.

Covalent bonding takes place between non-metals only.

Single BondDouble BondTriple Bond
2ē shared4ēs shared6ēs shared
PropertyReason
Low m.p. and b.p.Weak intermolecular forces of attraction between molecules
Usually liquid, gas or low m.p solidNo mobile ions/electrons
Don't conduct electricityNot required
Usually insoluble in water

Example:

Macromolecules

DiamondGraphiteSilicon Dioxide
Four bondsThree bondsMakes up sand
High m.p.Made of flat sheetsEach Si is bonded to 4 oxygen atoms, and each oxygen is bonded to 2 silicon atoms
Doesn't conductHeld together by weak forces so is soft ∴ used as a lubricant∴ it has a high m.p. and is hard, like diamond
Used for cutting as is srongest known substanceConducts electricity as it has one free e-

Melting point: high - structure made up of strong covalent bonds.

Electrical: don’t conduct electricity - have no mobile ions or electrons, except for graphite.

Strength: hard - exists in tetrahedral structure but graphite is soft.

Metallic Bonding

Positive ions held together by electrons -- acts like glue